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1 synthetic fibres industry
производство синтетических волокон
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synthetic fibres industry
[http://www.eionet.europa.eu/gemet/alphabetic?langcode=en]Тематики
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Англо-русский словарь нормативно-технической терминологии > synthetic fibres industry
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2 Carothers, Wallace Hume
[br]b. 27 April 1896 Burlington, Iowa, USAd. 29 April 1937 Philadelphia, Pennsylvania, USA[br]American chemist, inventor of nylon.[br]After graduating in chemistry, Carothers embarked on academic research at several universities, finally at Harvard University. His earliest published papers, from 1923, heralded the brilliance and originality of his later work. In 1928, Du Pont de Nemours persuaded him to forsake the academic world to lead their new organic-chemistry group in a programme of fundamental research at their central laboratories at Wilmington, Delaware. The next nine years were extraordinarily productive, yielding important contributions to theoretical organic chemistry and the foundation of two branches of chemical industry, namely the production of synthetic rubber and of wholly synthetic fibres.Carothers began work on high molecular weight substances yielding fibres and introduced polymerization by condensation: polymerization by addition was already known. He developed a clear understanding of the relation between the repeating structural units in a large molecule and its physical chemical properties. In 1931, Carothers found that chloroprene could be polymerized much faster than isoprene, the monomer in natural rubber. This process yielded polychloroprene or neoprene, a synthetic rubber with improved properties. Manufacture began the following year, and the material has continued to be used for speciality rubbers.There followed many publications announcing new condensations polymers. On 2 January 1935, he obtained a patent for the formation of new polyamides, including one from adipic acid and hexamethylenediamene. After four years of development work, which cost Du Pont some $27 million, this new polyamide, or nylon, reached the stage of commercial production, beginning on 23 October 1938. Nylon stockings appeared the following year and 64 million were sold during the first twelve months. However, Carothers saw none of this spectacular success: he had died by his own hand in 1937, after a long history of gradually intensifying depression.[br]Principal Honours and DistinctionsElected to the National Academy of Science 1936 (he was the first industrial organic chemist to be so honoured).BibliographyH.M.Whitby and G.S.Whitby, 1940, Collected Papers of Wallace H.Carothers on Polymerisation, New York.Further ReadingR.Adams, 1939, memoir, Biographical Memoirs of the National Academy of Sciences 20:293–309 (includes a complete list of Carothers's sixty-two scientific papers and most of his sixty-nine US patents).LRDBiographical history of technology > Carothers, Wallace Hume
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3 Bevan, Edward John
[br]b. 11 December 1856 Birkenhead, Englandd. 17 October 1921 London, England[br]English co-inventor of the " viscose rayon " process for making artificial silk.[br]Bevan began his working life as a chemist in a soap works at Runcorn, but later studied chemistry at Owens College, Manchester. It was there that he met and formed a friendship with C.F. Cross, with whom he started to work on cellulose. Bevan moved to a paper mill in Scotland but then went south to London, where he and Cross set up a partnership in 1885 as consulting and analytical chemists. Their work was mainly concerned with the industrial utilization of cellulose, and with the problems of the paper and jute industries. Their joint publication, A Text-book of Paper-making, which first appeared in 1888 and went into several editions, became the standard reference and textbook on the subject. The book has a long introductory chapter on cellulose.In 1892 Cross, Bevan and Clayton Beadle discovered viscose, or sodium cellulose xanthate, and took out the patent which was to be the foundation of the "viscose rayon" industry. They had their own laboratory at Station Avenue, Kew Gardens, where they carried out much work that eventually resulted in viscose: cellulose, usually in the form of wood pulp, was treated first with caustic soda and then with carbon disulphide to form the xanthate, which was then dissolved in a solution of dilute caustic soda to produce a viscous liquid. After being aged, the viscose was extruded through fine holes in a spinneret and coagulated in a dilute acid to regenerate the cellulose as spinnable fibres. At first there was no suggestion of spinning it into fibre, but the hope was to use it for filaments in incandescent electric light bulbs. The sheen on the fibres suggested their possible use in textiles and the term "artificial silk" was later introduced. Cross and Bevan also discovered the acetate "Celanese", which was cellulose triacetate dissolved in acetone and spun in air, but both inventions needed much development before they could be produced commercially.In 1892 Bevan turned from cellulose to food and drugs and left the partnership to become Public Analyst to Middlesex County Council, a post he held until his death, although in 1895 he and Cross published their important work Cellulose. He was prominent in the affairs of the Society of Public Analysts and became one of its officials.[br]Bibliography1888, with C.F.Cross, A Text-book of Papermaking.1892, with C.F.Cross and C.Beadle, British patent no. 8,700 (viscose). 1895, with C.F.Cross, Cellulose.Further ReadingObituary, 1921, Journal of the Chemical Society.Obituary, 1921, Journal of the Society of Chemical Industry.Edwin J.Beer, 1962–3, "The birth of viscose rayon", Transactions of the Newcomen Society 35 (an account of the problems of developing viscose rayon; Beer worked under Cross in the Kew laboratories).RLH -
4 Cross, Charles Frederick
[br]b. 11 December 1855 Brentwood, Middlesex, Englandd. 15 April 1935 Hove, England[br]English chemist who contributed to the development of viscose rayon from cellulose.[br]Cross was educated at the universities of London, Zurich and Manchester. It was at Owens College, Manchester, that Cross first met E.J. Bevan and where these two first worked together on the nature of cellulose. After gaining some industrial experience, Cross joined Bevan to set up a partnership in London as analytical and consulting chemists, specializing in the chemistry and technology of cellulose and lignin. They were at the Jodrell laboratory, Kew Gardens, for a time and then set up their own laboratory at Station Avenue, Kew Gardens. In 1888, the first edition of their joint publication A Textbook of Paper-making, appeared. It went into several editions and became the standard reference and textbook on the subject. The long introductory chapter is a discourse on cellulose.In 1892, Cross, Bevan and Clayton Beadle took out their historic patent on the solution and regeneration of cellulose. The modern artificial-fibre industry stems from this patent. They made their discovery at New Court, Carey Street, London: wood-pulp (or another cheap form of cellulose) was dissolved in a mixture of carbon disulphide and aqueous alkali to produce sodium xanthate. After maturing, it was squirted through fine holes into dilute acid, which set the liquid to give spinnable fibres of "viscose". However, it was many years before the process became a commercial operation, partly because the use of a natural raw material such as wood involved variations in chemical content and each batch might react differently. At first it was thought that viscose might be suitable for incandescent lamp filaments, and C.H.Stearn, a collaborator with Cross, continued to investigate this possibility, but the sheen on the fibres suggested that viscose might be made into artificial silk. The original Viscose Spinning Syndicate was formed in 1894 and a place was rented at Erith in Kent. However, it was not until some skeins of artificial silk (a term to which Cross himself objected) were displayed in Paris that textile manufacturers began to take an interest in it. It was then that Courtaulds decided to investigate this new fibre, although it was not until 1904 that they bought the English patents and developed the first artificial silk that was later called "rayon". Cross was also concerned with the development of viscose films and of cellulose acetate, which became a rival to rayon in the form of "Celanese". He retained his interest in the paper industry and in publishing, in 1895 again collaborating with Bevan and publishing a book on Cellulose and other technical articles. He was a cultured man and a good musician. He was elected a Fellow of the Royal Society in 1917.[br]Principal Honours and DistinctionsFRS 1917.Bibliography1888, with E.J.Bevan, A Text-book of Papermaking. 1892, British patent no. 8,700 (cellulose).Further ReadingObituary Notices of the Royal Society, 1935, London. Obituary, 1935, Journal of the Chemical Society 1,337. Chambers Concise Dictionary of Scientists, 1989, Cambridge.Edwin J.Beer, 1962–3, "The birth of viscose rayon", Transactions of the Newcomen Society 35 (an account of the problems of developing viscose rayon; Beer worked under Cross in the Kew laboratories).C.Singer (ed.), 1978, A History of Technology, Vol. VI, Oxford: Clarendon Press.RLHBiographical history of technology > Cross, Charles Frederick
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5 Staudinger, Hermann
[br]b. 23 March 1881 Worms, Germanyd. 8 September 1965 Freiberg im Breisgau, Germany[br]German chemist, founder of polymer chemistry.[br]Staudinger studied chemistry at the universities of Halle, Darmstadt and Munich, originally as a preparation for botanical studies, but chemistry claimed his full attention. He followed an academic career, with professorships at Karlsruhe in 1908, Zurich in 1912 and Freiberg from 1926 until his retirement in 1951. Staudinger began his work as an organic chemist by following well-established lines of research, but from 1920 he struck out in a new direction. Until that time, rubber and other apparently non-crystalline materials with high molecular weight were supposed to consist of a disordered collection of small molecules. Staudinger investigated the structure of rubber and realized that it was made up of very large molecules with many basic groups of atoms held together by normal chemical bonds. Substances formed in this way are known as "polymers". Staudinger's views first met with opposition, but he developed methods of determining the molecular weights of these "high polymers". Finally, the introduction of X-ray crystallographic investigation of chemical structure confirmed his views. This discovery has proved to be the basis of a new branch of chemistry with momentous consequences for industry. From it stemmed the synthetic rubber, plastics, fibres, adhesives and other industries, with all their multifarious applications in everyday life. The Staudinger equation, linking viscosity with molecular weight, is still widely used, albeit with some reservations, in the polymer industry.During the 1930s, Staudinger turned his attention to biopolymers and foresaw the discovery some twenty years later that these macromolecules were the building blocks of life. In 1953 he belatedly received the Nobel Prize in Chemistry.[br]Principal Honours and DistinctionsNobel Prize in Chemistry 1953.Bibliography1961, Arbeitserinnerungen, Heidelberg; pub. in English, 1970 as From Organic Chemistry to Macromolecules, New York (includes a comprehensive bibliography of 644 items).Further ReadingE.Farber, 1963, Nobel Prize Winners in Chemistry, New York.R.C.Olby, 1970, "The macromolecular concept and the origins of molecular biology", J. Chem. Ed. 47:168–74.LRD -
6 Whinfield, John Rex
[br]b. 16 February 1901 Sutton, Surrey, Englandd. 6 July 1955 Dorking, Surrey, England[br]English inventor ofTerylene.[br]Whinfield was educated at Merchant Taylors' School and Caius College, Cambridge, where he studied chemistry. Before embarking on his career as a research chemist, he worked as an un-paid assistant to the chemist C.F. Cross, who had taken part in the discovery of rayon. Whinfield then joined the Calico Printers' Association. There his interest was aroused by the discovery of nylon by W.H. Carothers to seek other polymers which could be produced in fibre form, usable by the textile industries. With his colleague J.T. Dickson, he discovered in 1941 that a polymerized condensate of terephthalic acid and ethylene glycol, polyethylene terephthgal-late, could be drawn into strong fibres. Whinfield and Dickson filed a patent application in the same year, but due to war conditions it was not published until 1946. The Ministry of Supply considered that the new material might have military applications and undertook further research and development. Its industrial and textile possibilities were evaluated by Imperial Chemical Industries (ICI) in 1943 and "Terylene", as it came to be called, was soon recognized as being as important as nylon.In 1946, Dupont acquired rights to work the Calico Printers' Association patent in the USA and began large-scale manufacture in 1954, marketing the product under the name "Dacron". Meanwhile ICI purchased world rights except for the USA and reached the large-scale manufacture stage in 1955. A new branch of the textile industry has grown up from Whinfield's discovery: he lived to see most people in the western world wearing something made of Terylene. It was one of the major inventions of the twentieth century, yet Whinfield, perhaps because he published little, received scant recognition, apart from the CBE in 1954.[br]Principal Honours and DistinctionsCBE 1954.Further ReadingObituary, 1966, The Times (7 July).Obituary, 1967, Chemistry in Britain 3:26.J.Jewkes, D.Sawers and R.Stillerman, 1969, The Sources of Invention, 2nd edn, London: Macmillan.LRD
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